A High Efficiency Electrodeposited Cu2ZnSnS4 Solar Cell

被引：513

作者：

Ahmed, Shafaat ^{[1
]}

Reuter, Kathleen B. ^{[1
]}

Gunawan, Oki ^{[1
]}

Guo, Lian ^{[1
]}

Romankiw, Lubomyr T. ^{[1
]}

Deligianni, Hariklia ^{[1
]}

机构：

[1] IBM Corp, Thomas J Watson Res Ctr, Yorktown Hts, NY 10598 USA

来源：

ADVANCED ENERGY MATERIALS | 2012年 / 2卷 / 02期

关键词：

Cu2ZnSnS4; electrodeposition; kesterites; metal stack; thin film solar cells; THIN-FILMS; MATERIALS AVAILABILITY; OPTICAL-PROPERTIES; PHOTOVOLTAICS; SULFURIZATION;

D O I：

10.1002/aenm.201100526

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

High-performance Cu 2ZnSnS 4 photovoltaic devices are demonstrated using electrodeposition of metal stacks and annealing of a CuZnSn precursor in a sulfur atmosphere. A champion electroplated Cu 2ZnSnS 4 solar cell achieves a power conversion efficiency of 7.3%, which is a record efficiency for electrodeposited Cu 2ZnSnS 4 solar devices. The device performance points to electrodeposition and annealing as a low-cost and viable approach to earth-abundant solar cell fabrication. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：253 / 259

页数：7

共 39 条

[1]

Andersson BA, 2000, PROG PHOTOVOLTAICS, V8, P61, DOI 10.1002/(SICI)1099-159X(200001/02)8:1<61::AID-PIP301>3.0.CO

[2]

2-6

[3]

Andricacos P. C., [No title captured], Patent No. [US 5,516,412, 5516412]

[4]

[Anonymous], APPL PHYS LETT

[5]

[Anonymous], PROG PHOTOVOLT RES A

[6]

[Anonymous], BAS EN SCI WORKSH SO

[7] Preparationof Cu2ZnSnS4 thin films by sulfurization of co-electroplated Cu-Zn-Sn precursors [J].

Araki, Hideaki ;

Kubo, Yuki ;

Jimbo, Kazuo ;

Maw, Win Shwe ;

Katagiri, Hironori ;

Yamazaki, Makoto ;

Oishi, Koichiro ;

Takeuchi, Akiko .

PHYSICA STATUS SOLIDI C - CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 6, NO 5, 2009, 6 (05) :1266-1268

[8] Device characteristics of a 10.1% hydrazine-processed Cu2ZnSn(Se,S)4 solar cell [J].

Barkhouse, D. Aaron R. ;

Gunawan, Oki ;

Gokmen, Tayfun ;

Todorov, Teodor K. ;

Mitzi, David B. .

PROGRESS IN PHOTOVOLTAICS, 2012, 20 (01) :6-11

[9] Thin films: ready for their close-up? [J].

Butler, Declan .

NATURE, 2008, 454 (7204) :558-559

[10] The Next Frontier: Electrodeposition for Solar Cell Fabrication [J].

Deligianni, Hariklia ;

Ahmed, Shafaat ;

Romankiw, Lubomyr T. .

ELECTROCHEMICAL SOCIETY INTERFACE, 2011, 20 (02) :47-53

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