Nickel-oxido structure of a water-oxidizing catalyst film

被引：104

作者：

Risch, Marcel ^{[1
]}

Klingan, Katharina ^{[1
]}

Heidkamp, Jonathan ^{[1
]}

Ehrenberg, David ^{[1
]}

Chernev, Petko ^{[1
]}

Zaharieva, Ivelina ^{[1
]}

Dau, Holger ^{[1
]}

机构：

[1] Free Univ Berlin, FB Phys, D-14195 Berlin, Germany

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 43期

关键词：

ABSORPTION FINE-STRUCTURE; OXYGEN-EVOLVING CATALYST; MANGANESE HYDROUS OXIDES; COORDINATION CHEMISTRY; LANIO3; PEROVSKITE; PHOTOSYSTEM-II; REDUCED FORMS; BOND VALENCE; SPECTROSCOPY; OXIDATION;

D O I：

10.1039/c1cc15072c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The atomic structure of an electrodeposited Ni catalyst film is dominated by extensive di-mu-oxido bridging between Ni(III/IV) ions, as revealed by X-ray absorption spectroscopy. The structure is surprisingly similar to that of an analogous Co-based film and colloidal Mn-based catalysts. Structural requirements for water oxidation are discussed.

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页码：11912 / 11914

页数：3

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