Planar, twisted, and trans-bent: Conformational flexibility of neutral diborenes

被引：181

作者：

Wang, Yuzhong

Quillian, Brandon

Wei, Pingrong

Xie, Yaoming

Wannere, Chaitanya S.

King, R. Bruce

Schaefer, Henry F., III

Schleyer, Paul v. R. ^{[1
]}

Robinson, Gregory H.

机构：

[1] Univ Georgia, Dept Chem, Athens, GA 30602 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 11期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1021/ja800257j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The potassium graphite reduction of R'BBr3 (R'= :C(N(2,4,6-Me3C6H2)CH)(2)) in Et2O led to the isolation of 3 (R'(H) B=B(H)R') and 4 (R'(H)(2)B-B(H)(2)R'), with B=B double and B-B single bonds, respectively. These compounds were characterized by single-crystal X-ray diffraction, H-1 and B-11 NMR, and elemental analyses. Neutral diborene 3 exhibits polymorphic planar (3a), twisted (3b), and trans-bent (3c) geometries in the solid state.

引用

收藏

页码：3298 / +

页数：3

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