A novel pyrolyzed polyacrylonitrile-sulfur@MWCNT composite cathode material for high-rate rechargeable lithium/sulfur batteries

被引:202
作者
Yin, Lichao [1 ]
Wang, Jiulin [1 ]
Yang, Jun [1 ]
Nuli, Yanna [1 ]
机构
[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Shanghai 200030, Peoples R China
基金
中国国家自然科学基金;
关键词
CARBON NANOTUBES; ELECTRODE;
D O I
10.1039/c1jm00047k
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel pPAN-S@ MWCNT core-shell composite material is prepared via in situ polymerization of acrylonitrile on the surface of MWCNT, mixing with sulfur and final pyrolysis. The homogenous dispersion and integration of MWCNT in the composite create an electronically conductive network and reinforce the structural stability, leading to the outstanding electrochemical performances as a cathode material for rechargeable lithium/sulfur batteries.
引用
收藏
页码:6807 / 6810
页数:4
相关论文
共 21 条
[1]  
Chaudhuri D, 2001, ADV MATER, V13, P1548, DOI 10.1002/1521-4095(200110)13:20<1548::AID-ADMA1548>3.0.CO
[2]  
2-S
[3]   Modification of Multiwall Carbon Nanotubes via Soap-Free Emulsion Polymerization of Acrylonitrile [J].
Cheng, Zhenping ;
Pan, Qinmin ;
Rempel, Garry L. .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2010, 48 (10) :2057-2062
[4]   Improvement of cycle property of sulfur electrode for lithium/sulfur battery [J].
Choi, Young-Jin ;
Kim, Ki-Won ;
Ahn, Hyo-Jun ;
Ahn, Jou-Hyeon .
JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 449 (1-2) :313-316
[5]   PHASE EQUILIBRIA IN LITHIUM-CHALCOGEN SYSTEMS .2. LITHIUM-SULFUR [J].
CUNNINGHAM, PT ;
CAIRNS, EJ ;
JOHNSON, SA .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1972, 119 (11) :1448-+
[6]   Evidence for large inner reorganization energies in the reduction of diaryl disulfides: Toward a mechanistic link between concerted and stepwise dissociative electron transfers? [J].
Daasbjerg, K ;
Jensen, H ;
Benassi, R ;
Taddei, F ;
Antonello, S ;
Gennaro, A ;
Maran, F .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (08) :1750-1751
[7]  
Dean J.A., 1985, LANGES HDB CHEM, V13
[8]   Effect of multiwalled carbon nanotubes on electrochemical properties of lithium sulfur rechargeable batteries [J].
Han, SC ;
Song, MS ;
Lee, H ;
Kim, HS ;
Ahn, HJ ;
Lee, JY .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (07) :A889-A893
[9]   Expansion and shrinkage of the sulfur composite electrode in rechargeable lithium batteries [J].
He, Xiangming ;
Ren, Jianguo ;
Wang, Li ;
Pu, Weihua ;
Jiang, Changyin ;
Wan, Chunrong .
JOURNAL OF POWER SOURCES, 2009, 190 (01) :154-156
[10]  
Ji XL, 2009, NAT MATER, V8, P500, DOI [10.1038/NMAT2460, 10.1038/nmat2460]