Photochemical oxidation of hydrogenated boron-doped diamond surfaces

被引：93

作者：

Boukherroub, R

Wallart, X

Szunerits, S

Marcus, B

Bouvier, P

Mermoux, M

机构：

[1] IEMN, CNRS 8520, F-59652 Villeneuve Dascq, France

[2] UJF, INPG, LEPMI, F-38402 St Martin Dheres, France

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2005年 / 7卷 / 09期

关键词：

boron-doped polycrystalline diamond; photochemical oxidation; electrochemical properties; surface chemical reactivity;

D O I：

10.1016/j.elecom.2005.05.010

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

We describe the photochemical oxidation of polycrystalline boron-doped diamond films by UV irradiation in air at room temperature. The reaction generates surface hydroxyl groups that have been coupled with perfluorodecyl trichlorosilane to yield an organic layer covalently attached to the diamond surface. The resulting surfaces were characterized using X-ray photoelectron spectroscopy, contact angle and cyclic voltammetry. (c) 2005 Elsevier B.V. All rights reserved.

引用

收藏

页码：937 / 940

页数：4

相关论文

共 26 条

[1] VAPOR-PHASE OXIDATION OF DIAMOND SURFACES IN O2 STUDIED BY DIFFUSE-REFLECTANCE FOURIER-TRANSFORM INFRARED AND TEMPERATURE-PROGRAMMED DESORPTION SPECTROSCOPY [J].

ANDO, T ;

YAMAMOTO, K ;

ISHII, M ;

KAMO, M ;

SATO, Y .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1993, 89 (19) :3635-3640

[2] SILANIZATION OF SOLID SUBSTRATES - A STEP TOWARD REPRODUCIBILITY [J].

BRZOSKA, JB ;

BENAZOUZ, I ;

RONDELEZ, F .

LANGMUIR, 1994, 10 (11) :4367-4373

[3] Biotin grafting on boron-doped diamond [J].

Delabouglise, D ;

Marcus, B ;

Mermoux, M ;

Bouvier, P ;

Chane-Tune, J ;

Petit, JP ;

Mailley, P ;

Livache, T .

CHEMICAL COMMUNICATIONS, 2003, (21) :2698-2699

[4] A sequential Raman analysis of the growth of diamond films on silicon substrates in a microwave plasma assisted chemical vapor deposition reactor [J].

Fayette, L ;

Marcus, B ;

Mermoux, M ;

Rosman, N ;

Abello, L ;

Lucazeau, G .

JOURNAL OF MATERIALS RESEARCH, 1997, 12 (10) :2686-2698

[5] IN-SITU RAMAN-SPECTROSCOPY DURING DIAMOND GROWTH IN A MICROWAVE PLASMA REACTOR [J].

FAYETTE, L ;

MARCUS, B ;

MERMOUX, M ;

ROSMAN, N ;

ABELLO, L ;

LUCAZEAU, G .

JOURNAL OF APPLIED PHYSICS, 1994, 76 (03) :1604-1608

[6] Electrochemical performance of diamond thin-film electrodes from different commercial sources [J].

Fischer, AE ;

Show, Y ;

Swain, GM .

ANALYTICAL CHEMISTRY, 2004, 76 (09) :2553-2560

[7] Influence of the environment on the surface conductivity of chemical vapor deposition diamond [J].

Foord, JS ;

Lau, CH ;

Hiramatsu, M ;

Jackman, RB ;

Nebel, CE ;

Bergonzo, P .

DIAMOND AND RELATED MATERIALS, 2002, 11 (3-6) :856-860

[8] An investigation of the surface reactivity of diamond photocathodes with molecular and atomic oxygen species [J].

Foord, JS ;

Hian, LC ;

Jackman, RB .

DIAMOND AND RELATED MATERIALS, 2001, 10 (3-7) :710-714

[9] Electrochemically induced surface modifications of boron-doped diamond electrodes:: an X-ray photoelectron spectroscopy study [J].

Goeting, CH ;

Marken, F ;

Gutiérrez-Sosa, A ;

Compton, RG ;

Foord, JS .

DIAMOND AND RELATED MATERIALS, 2000, 9 (3-6) :390-396

[10] Standard electrochemical behavior of high-quality, boron-doped polycrystalline diamond thin-film electrodes [J].

Granger, MC ;

Witek, M ;

Xu, JS ;

Wang, J ;

Hupert, M ;

Hanks, A ;

Koppang, MD ;

Butler, JE ;

Lucazeau, G ;

Mermoux, M ;

Strojek, JW ;

Swain, GM .

ANALYTICAL CHEMISTRY, 2000, 72 (16) :3793-3804