Lithium insertion in an oriented nanoporous oxide with a tunnel structure:: Ti2Nb2O9

被引：61

作者：

Colin, J. -F. ^{[1
]}

Pralong, V. ^{[1
]}

Hervieu, M. ^{[1
]}

Caignaert, V. ^{[1
]}

Raveau, B. ^{[1
]}

机构：

[1] CNRS, ENSICAEN, Lab CRISMAT, UMR 6508, F-14050 Caen, France

来源：

CHEMISTRY OF MATERIALS | 2008年 / 20卷 / 04期

关键词：

D O I：

10.1021/cm702978g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The electrochemical study of the empty tunnel structure Ti2Nb2O9 shows that it can intercalate lithium reversibly, through a solid-solution process, leading to the phase Li4Ti2Nb2O9. The high-resolution electron microscopy study of this phase shows that Ti2Nb2O9 exhibits an exceptional nanoporosity, involving the formation of aligned holes throughout the whole microcrystal, which may favor, together with the presence of tunnels, the diffusion of lithium during the insertion. The reversible capacity of this phase, of 125 mAh/g at 1.57 V vs Li/Li+, after 30 cycles, shows its great reversibility.

引用

页码：1534 / 1540

页数：7

共 19 条

[1] Lithium-ion intercalation into TiO2-B nanowires [J].

Armstrong, AR ;

Armstrong, G ;

Canales, J ;

García, R ;

Bruce, PG .

ADVANCED MATERIALS, 2005, 17 (07) :862-+

[2] TiO2(B) nanotubes as negative electrodes for rechargeable lithium batteries [J].

Armstrong, G ;

Armstrong, AR ;

Canales, J ;

Bruce, PG .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2006, 9 (03) :A139-A143

[3] LITHIUM INSERTION IN WADSLEY-ROTH PHASES BASED ON NIOBIUM OXIDE [J].

CAVA, RJ ;

MURPHY, DW ;

ZAHURAK, SM .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1983, 130 (12) :2345-2351

[4] A novel layered titanoniobate LiTiNbO5:: Topotactic synthesis and electrochemistry versus lithium [J].

Colin, J. -F. ;

Pralong, V. ;

Caignaert, V. ;

Hervieu, M. ;

Raveau, B. .

INORGANIC CHEMISTRY, 2006, 45 (18) :7217-7223

[5] SPINEL ANODES FOR LITHIUM-ION BATTERIES [J].

FERG, E ;

GUMMOW, RJ ;

DEKOCK, A ;

THACKERAY, MM .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (11) :L147-L150

[6] High lithium electroactivity of nanometer-sized rutile TiO2 [J].

Hu, Yong-Sheng ;

Kienle, Lorenz ;

Guo, Yu- Guo ;

Maier, Joachim .

ADVANCED MATERIALS, 2006, 18 (11) :1421-+

[7]

HUANG SY, 1995, J ELECTROCHEM SOC, V142, P142

[8] TIO2(B) A NEW FORM OF TITANIUM-DIOXIDE AND THE POTASSIUM OCTATITANATE K2TI8O17 [J].

MARCHAND, R ;

BROHAN, L ;

TOURNOUX, M .

MATERIALS RESEARCH BULLETIN, 1980, 15 (08) :1129-1133

[9] Preparation of particulate Li4Ti5O12 having excellent characteristics as an electrode active material for power storage cells [J].

Nakahara, K ;

Nakajima, R ;

Matsushima, T ;

Majima, H .

JOURNAL OF POWER SOURCES, 2003, 117 (1-2) :131-136

[10] ZERO-STRAIN INSERTION MATERIAL OF LI[LI1/3TI5/3]O-4 FOR RECHARGEABLE LITHIUM CELLS [J].

OHZUKU, T ;

UEDA, A ;

YAMAMOTO, N .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (05) :1431-1435

← 1 2 →