Synthesis of cagelike polymer microspheres with hollow core/porous shell structures by self-assembly of latex particles at the emulsion droplet interface

被引：124

作者：

He, XD ^{[1
]}

Ge, XW ^{[1
]}

Liu, HR ^{[1
]}

Wang, MZ ^{[1
]}

Zhang, ZC ^{[1
]}

机构：

[1] Univ Sci & Technol China, Dept Polymer Sci & Engn, Hefei 230026, Anhui, Peoples R China

来源：

CHEMISTRY OF MATERIALS | 2005年 / 17卷 / 24期

关键词：

D O I：

10.1021/cm051694j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The synthesis of a cagelike polymer microspheres with a hollow core/porous shell structure by latex self-assembly at the emulsion droplet interface, was analyzed. The first step of the synthetic procedure is to prepare a stable emulsion from surface-sulfonated polystyrene (PS) particle by self-assembly of PS particles at the water monomer droplet interface. The hydrophilicity of PS particles was adjusted by controlling the sulfonation time and the density of chemi-grafted SO3H group on the particle surfaces. The results show that PS particles sulfonated for 21 h gave the most stable emulsion system.

引用

页码：5891 / 5892

页数：2

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