Dynamic and fluorescent nanoscale phenanthroline/terpyridine zinc(II) ladders.: Self-recognition in unlike ligand/like metal coordination scenarios

被引：107

作者：

Schmittel, M

Kalsani, V

Kishore, RSK

Cölfen, H

Bats, JW

机构：

[1] Univ Siegen, Ctr Micro & Nanochem & Engn Organ Chem 1, D-57068 Siegen, Germany

[2] Max Planck Inst Colloids & Interfaces, D-14424 Potsdam, Germany

[3] Goethe Univ Frankfurt, Inst Organ Chem & Chem Biol, D-60439 Frankfurt, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 33期

关键词：

D O I：

10.1021/ja0525096

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new coordination kit, the HETTAP approach, is described, which allows one to prepare supramolecular heteroleptic metal phenanthroline/terpyridine racks and ladders in basically quantitative yield. Due to the dynamic nature of the nanoladder structures, a two-step double-transmetalation and scenarios with like metal/unlike ligand recognition were realized. Copyright © 2005 American Chemical Society.

引用

收藏

页码：11544 / 11545

页数：2

相关论文

共 29 条

[1] Inorganic arrays via multicomponent self-assembly: The spontaneous generation of ladder architectures [J].

Baxter, PNW ;

Hanan, GS ;

Lehn, JM .

CHEMICAL COMMUNICATIONS, 1996, (17) :2019-2020

[2]

Baxter PNW, 2000, CHEM-EUR J, V6, P4140, DOI 10.1002/1521-3765(20001117)6:22<4140::AID-CHEM4140>3.0.CO

[3]

2-5

[4] Programmed self-sorting of coiled coils with leucine and hexafluoroleucine cores [J].

Bilgiçer, B ;

Xing, X ;

Kumar, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (47) :11815-11816

[5] Coordination assemblies from a Pd(II)-cornered square complex [J].

Fujita, M ;

Tominaga, M ;

Hori, A ;

Therrien, B .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :369-378

[6] Dominant/recessive behavior in the expression of molecular information: Self-assembly of inorganic macrocyclic architectures containing coordinatively unsaturated ligands [J].

Funeriu, DP ;

Rissanen, K ;

Lehn, JMP .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2001, 98 (19) :10546-10551

[7] Zinc(II)-templated synthesis of a [2]-catenane 2,2′,6′,2"-terpyridine-incorporating cycle and a 1,10-phenanthroline-containing ring [J].

Hamann, C ;

Kern, JM ;

Sauvage, JP .

INORGANIC CHEMISTRY, 2003, 42 (06) :1877-1883

[8] Self-assembly of a heteroduplex helicate from two different ligand strands and Cu(II) cations [J].

Hasenknopf, B ;

Lehn, JM ;

Baum, G ;

Fenske, D .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1996, 93 (04) :1397-1400

[9] Recent developments in the supramolecular chemistry of terpyridine-metal complexes [J].

Hofmeier, H ;

Schubert, US .

CHEMICAL SOCIETY REVIEWS, 2004, 33 (06) :373-399

[10]

Holliday BJ, 2001, ANGEW CHEM INT EDIT, V40, P2022, DOI 10.1002/1521-3773(20010601)40:11<2022::AID-ANIE2022>3.0.CO