Macrocyclic oxonium ylide formation and internal [2,3]-sigmatropic rearrangement. Catalyst influence on selectivity

被引:26
作者
Doyle, MP
Peterson, CS
机构
[1] Department of Chemistry, Trinity University, San Antonio
关键词
D O I
10.1016/S0040-4039(97)01160-X
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The formation of 13-membered ring oxonium ylides and their subsequent stereocontrolled [2,3]-sigmatropic rearrangement to 10-membered ring lactones occurs in catalyst dependent competition with macrocylic cyclopropanation. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:5265 / 5268
页数:4
相关论文
共 26 条