Stereoselective synthesis of the bicyclic core structure of the highly oxidised sesquiterpene neoliacinic acid

被引：38

作者：

Clark, JS ^{[1
]}

Dossetter, AG ^{[1
]}

Whittingham, WG ^{[1
]}

机构：

[1] ZENECA AGROCHEM,JEALOTTS HILL RES STN,BRACKNELL RG42 6ET,BERKS,ENGLAND

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 31期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/0040-4039(96)01136-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The bicyclic core (3) of the sesquiterpene neoliacinic acid (1) has been constructed in a stereoselective manner by [2,3]-sigmatropic ring-expansion of an oxonium ylide generated catalytically from the alpha-diazo ketone 4. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：5605 / 5608

页数：4

共 24 条

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[6] A SHORT SYNTHESIS OF (+/-)-DECARESTRICTINE-L
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[8] Doyle M.P, 1995, COMPREHENSIVE ORGANO, P421
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[J]. TETRAHEDRON LETTERS, 1992, 33 (19) : 2709 - 2712

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