A new approach to the stereoselective carbodiazenylation of olefins by macrocyclization

被引：16

作者：

Heinrich, Markus R. ^{[1
]}

Blank, Olga ^{[1
]}

Wetzel, Alexander ^{[1
]}

机构：

[1] Tech Univ Munich, D-85747 Garching, Germany

来源：

SYNLETT | 2006年 / 19期

关键词：

azo compounds; cyclizations; diastereoselectivity; macrocycles; radicals;

D O I：

10.1055/s-2006-951556

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reduction of bisaryldiazonium salts in the presence of olefins leads to macrocyclic azo compounds. Chiral auxiliaries incorporated in the bisaryldiazonium salt allow the stereochemical control of the newly formed carbon center.

引用

页码：3352 / 3354

页数：3

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