Signatures of reactive resonance: three case studies

被引:35
作者
Chao, SD [1 ]
Skodje, RT [1 ]
机构
[1] Univ Colorado, Dept Chem & Biochem, Campus Box 215, Boulder, CO 80309 USA
关键词
resonance; molecular beams; reaction dynamics;
D O I
10.1007/s00214-002-0366-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Recent advances in the study of short-lived reactive resonances are reviewed. Special emphasis is given to addressing the question of how reactive resonances might be observed in molecular beam scattering experiments. Three case studies are presented for simple triatomic systems that are believed to exhibit resonance phenomena: F + HD --> D + HF, F + H-2 --> H + HF, and H + HD --> D + H-2. It is seen that reactive resonances do strongly influence collision observables, but in a different way for each case. At this stage, there does not appear to be a unique resonance signature that can be applied to all reactions.
引用
收藏
页码:273 / 285
页数:13
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