Coordination complexes of the hydroxymethylphosphine FcCH2P(CH2OH), [Fc = (η5-C5H5)Fe(η5-C5H4)] and the x-ray crystal structure of the cationic gold bis(phosphine) complex [Au{FcCH2P(CH2OH)2}2]Cl

被引：11

作者：

Goodwin, NJ ^{[1
]}

Henderson, W ^{[1
]}

机构：

[1] Univ Waikato, Dept Chem, Hamilton, New Zealand

来源：

POLYHEDRON | 1998年 / 17卷 / 23-24期

关键词：

ferrocene; phosphine; hydroxymethyl; metal phosphine complexes; crystal structure;

D O I：

10.1016/S0277-5387(98)00211-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Platinum(II) and palladium(II) complexes MCl2L2 and the gold(I) complex [AuL2]Cl of the air-stable ferrocene-derived hydroxymethylphosphine FcCH(2)P(CH2OH)(2) (L) have been synthesised by ligand substitution reactions, and the eta(6)-p-cymene ruthenium(II) complex RuCl2(eta(6)-C10H14)L has been synthesised by a chloride bridge-splitting reaction of the dimer [RuCl2(eta(6)-C10H14)](2). The cationic gold complex has been the subject of a single-crystal X-ray diffraction study, which shows the presence of the expected linearly coordinated bis(phosphine)gold cation, hydrogen-bonded to the chloride counterion and a lattice water molecule. (C) 1998 Elsevier Science Ltd. All rights reserved.

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页码：4071 / 4077

页数：7

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