ω-phenylalkyl substituted amido functionalized ansa half-sandwich complexes of titanium and zirconium and metallacycles thereof as catalyst precursors for homogeneous ethylene polymerization

被引：25

作者：

Alt, HG ^{[1
]}

Reb, A ^{[1
]}

Kundu, K ^{[1
]}

机构：

[1] Univ Bayreuth, Anorgan Chem Lab, D-94550 Bayreuth, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 628卷 / 02期

关键词：

group; 4; metals; ansa half-sandwich complexes; metallacycles; ethylene polymerization; homogeneous polymerization;

D O I：

10.1016/S0022-328X(01)00780-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation and characterization of omega -phenylalkyl substituted ansa half-sandwich dichloride complexes of titanium and zirconium is described. These complexes react with butyllithium to give metallacycles via a CH activation reaction on the ortho position of the phenyl group. All complexes were used as catalyst precursors for homogeneous ethylene polymerization. The effect of the catalyst structure on the polyethylene properties is discussed. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：211 / 221

页数：11

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