Micellar electrokinetic chromatography

被引:28
作者
Otsuka, K [1 ]
Terabe, S [1 ]
机构
[1] Himeji Inst Technol, Fac Sci, Dept Mat Sci, Kamigori, Hyogo 6781297, Japan
关键词
D O I
10.1246/bcsj.71.2465
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A review of the research on micellar electrokinetic chromatography (MEKC), carried out mainly in our laboratory, is described from the viewpoints of (1) fundamental characteristics of MEKC, such as the separation principle, chromatographic parameters, selectivity and resolution, thermodynamic parameters, retention index, and band broadening; (2) selectivity manipulation, including effects of surfactants, temperature, pH, and various additives; (3) on-line coupling of MEKC with mass spectrometry; (4) applications, such as the separation of closely related compounds and enantiomer separations; and (5) on-line neutral sample concentration techniques.
引用
收藏
页码:2465 / 2481
页数:17
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