Cathodoluminescence of Cu diffusion in CdTe thin films for CdTe/CdS solar cells

被引:37
作者
Romero, MJ [1 ]
Albin, DS [1 ]
Al-Jassim, MM [1 ]
Wu, XZ [1 ]
Moutinho, HR [1 ]
Dhere, RG [1 ]
机构
[1] Natl Renewable Energy Lab, Golden, CO 80401 USA
关键词
D O I
10.1063/1.1515119
中图分类号
O59 [应用物理学];
学科分类号
摘要
We investigate the distribution of Cu acceptor states in CdTe thin films used in high-efficiency solar cells. These states are Cu-Cd and Cu-i(+)-V-Cd(-) complexes, which are relatively deep and shallow acceptors, respectively. Cathodoluminescence spectroscopy and imaging show that, first, Cu-Cd and Cu-i(+)-V-Cd(-) do not coexist and, second, the primary diffuser is represented by Cu-i(+)-V-Cd(-) complexes. Our results are used to discuss the effect of grain boundaries on Cu diffusion. (C) 2002 American Institute of Physics.
引用
收藏
页码:2962 / 2964
页数:3
相关论文
共 16 条
[1]  
[Anonymous], 2001, Proceedings of the 17th European Photovoltaic Solar Energy Conference
[2]  
CASTALDINI A, 1996, APPL PHYS LETT, V69, P3507
[3]   SPECTRAL RESOLUTION IN LOW-TEMPERATURE CATHODOLUMINESCENCE - APPLICATION TO CDTE [J].
CHAMONAL, JP ;
MOLVA, E ;
DUPUY, M ;
ACCOMO, R ;
PAUTRAT, JL .
PHYSICA B & C, 1983, 116 (1-3) :519-526
[4]   Copper migration in CdTe heterojunction solar cells [J].
Chou, HC ;
Rohatgi, A ;
Jokerst, NM ;
Thomas, EW ;
Kamra, S .
JOURNAL OF ELECTRONIC MATERIALS, 1996, 25 (07) :1093-1098
[5]   EFFECTS OF CU ON CDTE/CDS HETEROJUNCTION SOLAR-CELLS WITH AU/CU CONTACTS [J].
CHOU, HC ;
ROHATGI, A ;
THOMAS, EW ;
KAMRA, S ;
BHAT, AK .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (01) :254-259
[6]  
GESSERT TA, 2002, P 29 IEEE PHOT SPEC
[7]   Photoluminescence study of Cu diffusion and electromigration in CdTe [J].
Grecu, D ;
Compaan, AD .
APPLIED PHYSICS LETTERS, 1999, 75 (03) :361-363
[8]   Photoluminescence of Cu-doped CdTe and related stability issues in CdS/CdTe solar cells [J].
Grecu, D ;
Compaan, AD ;
Young, D ;
Jayamaha, U ;
Rose, DH .
JOURNAL OF APPLIED PHYSICS, 2000, 88 (05) :2490-2496
[9]   IDENTIFICATION OF THE CHLORINE-A CENTER IN CDTE [J].
HOFMANN, DM ;
OMLING, P ;
GRIMMEISS, HG ;
MEYER, BK ;
BENZ, KW ;
SINERIUS, D .
PHYSICAL REVIEW B, 1992, 45 (11) :6247-6250
[10]   Room-temperature detection of mobile impurities in compound semiconductors by transient ion drift [J].
Lyubomirsky, I ;
Rabinal, MK ;
Cahen, D .
JOURNAL OF APPLIED PHYSICS, 1997, 81 (10) :6684-6691