Ultrasonic speed of sound and derived thermodynamic properties of liquid 1,1,1,2,3,3,3-heptafluoropropane (HFC227ea) from 248 K to 333 K and pressures up to 65 MPa

被引:18
作者
Pires, PF [1 ]
Esperança, JMSS [1 ]
Guedes, HJR [1 ]
机构
[1] Univ Nova Lisboa, Fac Ciencias & Tecnol, Ctr Quim Fina & Biotecnol, Dept Quim, P-2825114 Caparica, Portugal
关键词
D O I
10.1021/je9902950
中图分类号
O414.1 [热力学];
学科分类号
摘要
This work reports experimental data of the speed of sound in liquid 1,1,1,2,3,3,3-heptafluoropropane (HFC227ea) from 248 K to 333 K and pressures up to 65 MPa, measured with a pulse-echo method. The results are fitted with a rational approximant. Derived thermodynamic properties are calculated, combining our experimental data with density and isobaric heat capacity values published by other authors. The results were compared with the data available in the literature.
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页码:496 / 501
页数:6
相关论文
共 11 条
[1]  
*ASM, 1979, MET HDB
[2]   MEASUREMENTS OF THE (T, P, RHO) BEHAVIOR OF 1,1,1,2,3,3,3-HEPTAFLUOROPROPANE (REFRIGERANT R227) IN THE LIQUID-PHASE [J].
KLOMFAR, J ;
HRUBY, J ;
SIFNER, O .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1994, 26 (09) :965-970
[3]  
KYOHARA O, 1978, J CHEM THERMODYN, V10, P721
[4]   VOLUMETRIC AND SPEED-OF-SOUND MEASUREMENTS FOR LIQUID TETRACHLOROMETHANE UNDER PRESSURE [J].
LAINEZ, A ;
MILLER, JF ;
ZOLLWEG, JA ;
STREETT, WB .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1987, 19 (12) :1251-1260
[5]   The speed of sound, and derived thermodynamic properties of liquid trifluoromethane (HFC23) from T = (258 to 303) K at pressures up to 65 MPa [J].
Pires, PF ;
Guedes, HJR .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1999, 31 (04) :479-490
[6]   The speed of sound and isentropic compressibility of liquid difluoromethane (HFC32) from T = (248 to 343) K and pressures up to 65 MPa [J].
Pires, PF ;
Guedes, HJR .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1999, 31 (01) :55-69
[7]   ACOUSTIC AND THERMODYNAMIC PROPERTIES OF METHANOL FROM 273-K TO 333-K AND AT PRESSURES TO 280-MPA [J].
SUN, TF ;
BISWAS, SN ;
TRAPPENIERS, NJ ;
TENSELDAM, CA .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1988, 33 (04) :395-398
[8]  
TUERK M, 1994, WAERMETECHNIK KAELTE, V79, P1
[9]  
WEBER LA, 1996, J CHEM ENG DATA, V41, P761
[10]  
White G. K., 1980, High Temperatures - High Pressures, V12, P311