A near-infrared electrochromic window based on an Sb-doped SnO2 electrode modified with a Ru-dioxolene complex

被引：58

作者：

García-Cañadas, J

Meacham, AP

Peter, LM

Ward, MD

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

[2] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

[3] Univ Autonoma Madrid, Dept Quim, E-28049 Madrid, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 26期

关键词：

cyclic voltammetry; electrochemistry; electrochromism; near infrared; ruthenium;

D O I：

10.1002/anie.200351338

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A window of opportunity: The ligand-centered redox activity of complex 1 (depicted) is exploited to make an electrochromic window, which demonstrates rapid and reversible changes in optical transmission at 940 nm. The window is made by adsorbing 1 onto a nanocrystalline Sb-doped SnO2 film attached to a transparent conducting substrate and cycling the applied potential through the catecholate/semiquinone redox couple.

引用

页码：3011 / 3014

页数：4

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