Enantioselective synthesis of functionalized α-amino acids via a chiral guanidine catalyzed Michael addition reaction

被引：90

作者：

Ma, DW ^{[1
]}

Cheng, KJ ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Bioorgan & Nat Prod Chem, Shanghai 200032, Peoples R China

来源：

TETRAHEDRON-ASYMMETRY | 1999年 / 10卷 / 04期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1016/S0957-4166(99)00038-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Several chiral guanidines were evaluated as catalysts for the Michael reaction of glycine derivatives 7 with acrylic esters 8. The best result (30.4% ee) was obtained when 7b was reacted with 8b under the catalysis of guanidine 1 in THF. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：713 / 719

页数：7

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