Factors controlling the relative stabilities of cis- and trans-[PtX2L2] isomers:: Chatt and Wilkins -: 50 years on

被引：85

作者：

Harvey, JN ^{[1
]}

Heslop, KM ^{[1
]}

Orpen, AG ^{[1
]}

Pringle, PG ^{[1
]}

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 02期

关键词：

D O I：

10.1039/b210939e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

DFT computations reveal that cis-trans preferences in [PtX2(PR3)(2)] species are due to a combination of electrostatics, pi-backbonding, antisymbiosis, and solvation effects.

引用

页码：278 / 279

页数：2

共 13 条

[1] ISOMERIZATION MECHANISMS OF SQUARE-PLANAR COMPLEXES [J].

ANDERSON, GK ;

CROSS, RJ .

CHEMICAL SOCIETY REVIEWS, 1980, 9 (02) :185-215

[2] On the relative magnitudes of cis and trans influences in metal complexes [J].

Anderson, KM ;

Orpen, AG .

CHEMICAL COMMUNICATIONS, 2001, (24) :2682-2683

[3] TRANS-INFLUENCE - ITS MEASUREMENT AND SIGNIFICANCE [J].

APPLETON, TG ;

CLARK, HC ;

MANZER, LE .

COORDINATION CHEMISTRY REVIEWS, 1973, 10 (3-4) :335-422

[4] THE NATURE OF THE CO-ORDINATE LINK .6. A COMPARISON OF EQUILIBRIA BETWEEN CIS(MET3)2PTCL2, AND TRANS-(MET3)2PTCL2, WHERE M = P, AS, AND SB [J].

CHATT, J ;

WILKINS, RG .

JOURNAL OF THE CHEMICAL SOCIETY, 1952, (NOV) :4300-4306

[5] Electronic effects on the stability of isomeric alkyl transition metal compounds [J].

Harvey, JN .

ORGANOMETALLICS, 2001, 20 (23) :4887-4895

[6]

HUHEEY JE, 1983, INORG CHEM, P526

[7] Wide bite angle diphosphines: Xantphos ligands in transition metal complexes and catalysis [J].

Kamer, PCJ ;

van Leeuwen, PWN ;

Reek, JNH .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (11) :895-904

[8] Remarkable differences in catalyst activity and selectivity for the production of methyl propanoate versus CO-ethylene copolymer by a series of palladium complexes of related C4-bridged diphosphines [J].

Knight, JG ;

Doherty, S ;

Harriman, A ;

Robins, EG ;

Betham, M ;

Eastham, GR ;

Tooze, RP ;

Elsegood, MRJ ;

Champkin, P ;

Clegg, W .

ORGANOMETALLICS, 2000, 19 (24) :4957-4967

[9] Impact of Cisplatin on the recent development of Pt coordination chemistry: a case study [J].

Lippert, B .

COORDINATION CHEMISTRY REVIEWS, 1999, 182 :263-295

[10] ANTISYMBIOSIS AND TRANS EFFECT [J].

PEARSON, RG .

INORGANIC CHEMISTRY, 1973, 12 (03) :712-713

← 1 2 →