Self-Assembly and Traveling Wave Ion Mobility Mass Spectrometry Analysis of Hexacadmium Macrocycles

被引:132
作者
Chan, Yi-Tsu [1 ]
Li, Xiaopeng [2 ]
Soler, Monica [1 ]
Wang, Jin-Liang [1 ]
Wesdemiotis, Chrys [1 ,2 ]
Newkome, George R. [1 ,2 ]
机构
[1] Univ Akron, Dept Polymer Sci, Akron, OH 44325 USA
[2] Univ Akron, Dept Chem, Akron, OH 44325 USA
基金
美国国家科学基金会;
关键词
GAS-PHASE; HEXAMERIC METALLOMACROCYCLES; COMPLEXES; CHEMISTRY; ARCHITECTURES; CONSTRUCTION; PRINCIPLE; POLYMERS; STEPWISE;
D O I
10.1021/ja907262c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Self-assembly of 1,3-di(4'-terpyridinyl)arenes by using the labile tpy-Cd(II)-tpy (where tpy = 2,2':6',2 ''-terpyridine) connectivity afforded access to hexacadmium macrocycles in high yield. These supramolecular assemblies were characterized by traveling wave ion mobility mass spectrometry (TWIM-MS).
引用
收藏
页码:16395 / +
页数:4
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