Remarks on the energetics of interfaces exhibiting constant phase element behaviour

被引：52

作者：

Lang, G

Heusler, KE

机构：

[1] Eotvos Lorand Univ, Dept Phys Chem, Budapest, Hungary

[2] Tech Univ Clausthal, D-38678 Clausthal Zellerfeld, Germany

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1998年 / 457卷 / 1-2期

基金：

匈牙利科学研究基金会;

关键词：

CPE; ideally polarisable electrode; impedance spectroscopy; energy dissipation;

D O I：

10.1016/S0022-0728(98)00301-5

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The energetics of electrified interfaces exhibiting constant phase element (CPE) behaviour is discussed. In the double layer region energy can be dissipated in various ways other than by charge transfer. Therefore, contrary to the statement in Zoltowski., J. Electroanal. Chem. 443 (1998) 149, an electrode with a double layer of CPE character can be an ideally polarisable electrode. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：257 / 260

页数：4

共 28 条

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