THE ARCHIMEDES LAW AND ELECTROCAPILLARITY

被引:2
作者
GRAFOV, BM
机构
[1] A.N. Frumkin Institute of Electrochemistry, the Academy of Sciences of Russia, Moscow
关键词
ARCHIMEDES LAW; VOLUME EXCESS; ELECTROCAPILLARITY;
D O I
10.1016/0013-4686(94)80087-1
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
For an ideally polarizable electrode it is found that among numerous volume Hansen excesses there exists one which is correlated with the Archimedes law and plays the role of the solution volume displaced due to occurrence of surface layer. This volume excess could be called the Archimedes volume excess or the Archimedes volume of the surface. The Archimedes volume of the surface can be expressed in the form of a partial thermodynamic derivative
引用
收藏
页码:467 / 469
页数:3
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