Soft-to-hard transformation of the mechanical properties of dynamic covalent polymers through component incorporation

被引：91

作者：

Ono, Takashi

Fujii, Shunsuke

Nobori, Tadahito

Lehn, Jean-Marie

机构：

[1] Univ Louis Pasteur Strasbourg 1, ISIS, F-67083 Strasbourg, France

[2] Mitsui Chem Inc, R&D Ctr, Chiba 2990265, Japan

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 01期

关键词：

D O I：

10.1039/b612035k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mechanical properties of acylhydrazone dynamic polymers may be converted from soft to hard by the incorporation of rigid monomeric components into the original soft polymer backbone, taking advantage of acylhydrazone bond exchange.

引用

页码：46 / 48

页数：3

共 18 条

[1] Molecular evolution: dynamic combinatorial libraries, autocatalytic networks and the quest for molecular function [J].

Cousins, GRL ;

Poulsen, SA ;

Sanders, JKM .

CURRENT OPINION IN CHEMICAL BIOLOGY, 2000, 4 (03) :270-279

[2] Toward complex matter: Supramolecular chemistry and self-organization [J].

Lehn, JM .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2002, 99 (08) :4763-4768

[3] Dynamers: dynamic molecular and supramolecular polymers [J].

Lehn, JM .

PROGRESS IN POLYMER SCIENCE, 2005, 30 (8-9) :814-831

[4]

Lehn JM, 1999, CHEM-EUR J, V5, P2455

[5] Toward self-organization and complex matter [J].

Lehn, JM .

SCIENCE, 2002, 295 (5564) :2400-2403

[6] Supramolecular polymer chemistry- scope and perspectives [J].

Lehn, JM .

POLYMER INTERNATIONAL, 2002, 51 (10) :825-839

[7]

Lehn JM, 1999, NATO ADV SCI I C-MAT, V527, P287

[8]

LEHN JM, 2005, SUPRAMOLECULAR POLYM, pCH1

[9] Optimizing the reversibility of hydrazone formation for dynamic combinatorial chemistry [J].

Nguyen, R ;

Huc, I .

CHEMICAL COMMUNICATIONS, 2003, (08) :942-943

[10] The size-selective synthesis of folded oligomers by dynamic templation [J].

Nishinaga, T ;

Tanatani, A ;

Oh, KC ;

Moore, JS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (21) :5934-5935

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