Novel cryptands containing thiourea units as a part of the macrocyclic framework

被引：13

作者：

Lukyanenko, NG ^{[1
]}

Kirichenko, TI ^{[1
]}

Scherbakov, SV ^{[1
]}

机构：

[1] Natl Acad Sci Ukraine, Dept Bioorgan Chem, AV Bogatsky Physicochem Inst, UA-65080 Odessa, Ukraine

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 2002年 / 21期

关键词：

D O I：

10.1039/b207902j

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkylation of diaza-18-crown-6 byN- substituted phthalimides having a terminal halogen in the substituent, and subsequent product interaction with hydrazine hydrate and acid hydrolysis gave corresponding N,N'-disubstituted diaza-18-crown-6-compounds with terminal primary amino groups in the side chains. The reaction of these compounds with carbon disulfide or with appropriate bis[oligo(ethyleneoxy)]isothiocyanates a afforded a series of novel cryptands with one or two thiourea units in one of the bridges.

引用

页码：2347 / 2351

页数：5

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