Universal features of the fluid to solid transition for attractive colloidal particles

被引:174
作者
Prasad, V [1 ]
Trappe, V
Dinsmore, AD
Segre, PN
Cipelletti, L
Weitz, DA
机构
[1] Harvard Univ, Dept Phys, Cambridge, MA 02138 USA
[2] Harvard Univ, DEAS, Cambridge, MA 02138 USA
[3] Univ Fribourg, Dept Phys, CH-1700 Fribourg, Switzerland
[4] Univ Massachusetts, Dept Phys, Amherst, MA 01003 USA
[5] NASA, George C Marshall Space Flight Ctr, Biophys Grp, Huntsville, AL 35812 USA
[6] Univ Montpellier 2, Dept Phys, F-34095 Montpellier, France
关键词
D O I
10.1039/b211107c
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 [物理化学]; 081704 [应用化学];
摘要
Attractive colloidal particles can exhibit a fluid to solid phase transition if the magnitude of the attractive interaction is sufficiently large, if the volume fraction is sufficiently high, and if the applied stress is sufficiently small. The nature of this fluid to solid transition is similar for many different colloid systems, and for many different forms of interaction. The jamming phase transition captures the common features of these fluid to solid translations, by unifying the behavior as a function of the particle volume fraction, the energy of interparticle attractions, and the applied stress. This paper describes the applicability of the jamming state diagram, and highlights those regions where the fluid to solid transition is still poorly understood. It also presents new data for gelation of colloidal particles with an attractive depletion interaction, providing more insight into the origin of the fluid to solid transition.
引用
收藏
页码:1 / 12
页数:12
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