Completely regioselective gamma-addition in aldol reaction of the conjugate base of the pentacarbonyl(propenylpyrrolidinocarbene)chromium(0) complex with aldehydes

被引：8

作者：

Baldoli, C

Hellier, P

Licandro, E

Maiorana, S

Manzotti, R

Papagni, A

机构：

[1] UNIV MILAN,DIPARTIMENTO CHIM ORGAN & IND,I-20133 MILAN,ITALY

[2] CNR,CTR STUDI SINTESI & STEREOCHIM SPECIALI SISTEMI O,I-20133 MILAN,ITALY

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 21期

关键词：

D O I：

10.1016/S0040-4039(97)00731-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The conjugate base of the pentacarbonyl(propenylpyrrolidinocarbene)chromium(C) complex reacts with aldehydes giving the corresponding aldols in good to excellent yields and in a completely gamma-regioselective manner. (C) 1997 Elsevier Science Ltd.

引用

页码：3769 / 3772

页数：4

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