Completely regioselective gamma-addition in aldol reaction of the conjugate base of the pentacarbonyl(propenylpyrrolidinocarbene)chromium(0) complex with aldehydes

被引:8
作者
Baldoli, C
Hellier, P
Licandro, E
Maiorana, S
Manzotti, R
Papagni, A
机构
[1] UNIV MILAN,DIPARTIMENTO CHIM ORGAN & IND,I-20133 MILAN,ITALY
[2] CNR,CTR STUDI SINTESI & STEREOCHIM SPECIALI SISTEMI O,I-20133 MILAN,ITALY
关键词
D O I
10.1016/S0040-4039(97)00731-4
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The conjugate base of the pentacarbonyl(propenylpyrrolidinocarbene)chromium(C) complex reacts with aldehydes giving the corresponding aldols in good to excellent yields and in a completely gamma-regioselective manner. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:3769 / 3772
页数:4
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