Structural architectures of charge-assisted, hydrogen-bonded, 2D layered amine ••• tetraphosphonate and zinc ••• tetraphosphonate ionic materials

被引:17
作者
Demadis, Konstantinos D. [1 ]
Barouda, Eleni [1 ]
Zhao, Hong [1 ]
Raptis, Raphael G. [1 ]
机构
[1] Univ Crete, Crystal Engn Growth & Design Lab, Dept Chem, GR-71003 Iraklion, Crete, Greece
关键词
Phosphonates; Organic-organic hybrids; Crystal structures; METALLIC CORROSION INHIBITION; ORGANIC HYBRID COMPOUNDS; SCALE GROWTH-INHIBITORS; CRYSTAL-STRUCTURE; 1,4-BUTANEBISPHOSPHONIC ACID; SUPRAMOLECULAR ISOMERISM; PHOSPHONATE CHEMISTRY; SOLUTION BEHAVIOR; NETWORKS; COMPLEXES;
D O I
10.1016/j.poly.2009.05.050
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The synthesis, characterization and structural analyses of ionic amine-phosphonate and hydrated metal ion-phosphonate compounds are reported. These are (en)(HDTMP), (NH4)(EDTMP), Zn(H2O)(6)(TDTMP) (en = ethylenediamine, HDTMP = hexamethylenediamine-tetrakis(methylenephosphonate), EDTMP diethylenediamine-tetrakis(methylenephosphonate), TDTMP = tetramethylenediamine-tetrakis(methylenephosphonate)). All three compounds are composed of discrete anions and cations. stabilized by intricate networks of hydrogen bonds, and form 2D layered architectures. (c) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3361 / 3367
页数:7
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