Separation and identification of aromatic acids in soil and the Everglades sediment samples using solid-phase microextraction followed by capillary zone electrophoresis

The separation and identification of aromatic acids in soil and the Everglades sediment samples was carried out using solid-phase microextraction (SPME) followed by capillary zone electrophoresis (CZE). The soil and sediment samples were subject to a series of sample treatments including oxidative hydrolysis with molecular oxygen in a sodium hydroxide solution, acidification and filtration. The aromatic acids in the sample filtrate were extracted using SPME with a polyacrylate-coated fiber. The acids adsorbed on the fiber were subsequently desorbed in methanol. The desorbed acids were then separated by CZE. Several aromatic acids (e.g., salicylic acid, p-coumaric acid, ferulic acid and vanillic acid) in both soil and sediment samples were separated, identified and quantified. The results of this study show that the combination of SPME with CZE is promising for environmental analysis. (C) 2002 Elsevier Science B.V. All rights reserved.