cis-Dioxomolybdenum(VI) complexes with tridentate and tetradentate Schiff base ligands.: Preparation, structures and inhibition of aerial oxidation of aldehydes

被引：88

作者：

Liimatainen, J ^{[1
]}

Lehtonen, A ^{[1
]}

Sillanpää, R ^{[1
]}

机构：

[1] Univ Turku, Dept Chem, FIN-20014 Turku, Finland

来源：

POLYHEDRON | 2000年 / 19卷 / 09期

关键词：

molybdenum complexes; aerial oxidation of aldehydes;

D O I：

10.1016/S0277-5387(00)00368-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and characterisation of foul monomeric cis-dioxomolybdenum(VI) complexes involving Schiff base ligands is described. Ligands were obtained by condensation of salicylaldehyde with substituted aminoethanols. [MoO2(acac)(2)] reacted with the prepared ligands forming six-coordinated cis-dioxoMo(VI) complexes. X-ray diffraction studies confirmed that ligands act in a tridentate manner and the sixth coordination site around Mo(VI) is occupied by methanol used as solvent. The complexes act as inhibitors in the oxidation of aldehydes by oxygen. (C) 2000 Elsevier Science Ltd All rights reserved.

引用

页码：1133 / 1138

页数：6

共 33 条

[11] Chiral phosphinoylalcohol complexes of monooxobis(peroxo)molybdenum(VI) and their use as asymmetric oxidants [J].