Influence of the formaldehyde content of waterbased melamine formaldehyde resins on physical properties of Scots pine impregnated therewith

被引：44

作者：

Lukowsky, D ^{[1
]}

机构：

[1] WKI, Fraunhofer Inst Holzforsch, D-38108 Braunschweig, Germany

来源：

HOLZ ALS ROH-UND WERKSTOFF | 2002年 / 60卷 / 05期

关键词：

D O I：

10.1007/s00107-002-0324-y

中图分类号：

TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];

学科分类号：

0805 ; 080502 ; 0822 ;

摘要：

This paper presents a systematical approach to the properties of wood impregnated with different waterbased melamine resins, to provide a basis for further research. Therefore, ten commercially available methylated melamine formaldehyde resins with increasing ratios of melamine to formaldehyde have been compared in respect of their influence in dimension stabilisation, sorption behaviour, formaldehyde emissions, and water repellency of the treated wood. The dimension stabilisation caused by resin molecules that penetrated the wooden cell wall correlated with the molar mass of the resins used for impregnation. The changes in the sorption isotherms were attributed to a bulking effect. Formaldehyde emissions during and after curing increased with an increasing ratio of formaldehyde to melamine in the resins.

引用

页码：349 / 355

页数：7

共 39 条

[21] MECHANISM OF THERMOPLASTICITY FOR CHEMICALLY-MODIFIED WOOD [J].

NAKANO, T .

HOLZFORSCHUNG, 1994, 48 (04) :318-324

[22] WOOD ENHANCEMENT TREATMENTS .1. IMPREGNATION OF SOUTHERN YELLOW PINE WITH MELAMINE-FORMALDEHYDE AND MELAMINE-AMMELINE-FORMALDEHYDE RESINS [J].

PITTMAN, CU ;

KIM, MG ;

NICHOLAS, DD ;

WANG, LC ;

KABIR, FRA ;

SCHULTZ, TP ;

INGRAM, LL .

JOURNAL OF WOOD CHEMISTRY AND TECHNOLOGY, 1994, 14 (04) :577-603

[23] DIFFUSION HINDRANCE VS WOOD-INDUCED CATALYTIC ACTIVATION OF MUF ADHESIVE POLYCONDENSATION [J].

PIZZI, A ;

PANAMGAMA, LA .

JOURNAL OF APPLIED POLYMER SCIENCE, 1995, 58 (01) :109-115

[24]

Ramiah M. V., 1970, Wood Science, V3, P120

[25] Electron energy loss spectroscopy (EELS) for quantification of cell-wall penetration of a melamine resin [J].

Rapp, AO ;

Bestgen, H ;

Adam, W ;

Peck, RD .

HOLZFORSCHUNG, 1999, 53 (02) :111-117

[26]

RAPP AO, 1995, 40047

[27]

RAPP AO, 1996, 40061

[28]

ROWELL RM, 1991, P INT S CHEM MOD WOO, P75

[29] INVESTIGATION OF MELAMINE-FORMALDEHYDE CURE BY FOURIER-TRANSFORM RAMAN-SPECTROSCOPY [J].

SCHEEPERS, ML ;

GELAN, JM ;

CARLEER, RA ;

ADRIAENSENS, PJ ;

VANDERZANDE, DJ ;

KIP, BJ ;

BRANDTS, PM .

VIBRATIONAL SPECTROSCOPY, 1993, 6 (01) :55-69

[30] CONTRIBUTIONS ON DIMENSIONAL STABILIZATION OF WOOD WITH POLYETHYLENE GLYCOL .I. BASIC INVESTIGATIONS ON DIMENSIONAL STABILIZATION OF WOOD WITH POLYETHYLENE GLYCOL [J].

SCHNEIDE.A .

HOLZ ALS ROH-UND WERKSTOFF, 1969, 27 (06) :209-&

← 1 2 3 4 →