Low temperature CO oxidation over unsupported nanoporous gold

被引：572

作者：

Xu, Caixia

Su, Jixin

Xu, Xiaohong

Liu, Pengpeng

Zhao, Hongjuan

Tian, Fang

Ding, Yi ^{[1
]}

机构：

[1] Shandong Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Colloid & Interface Chem, Jinan 250100, Peoples R China

[2] Shandong Univ, Sch Environm Sci & Engn, Jinan 250100, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 01期

关键词：

D O I：

10.1021/ja0675503

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Supported Au nanoclusters are well-known for their unusual properties in catalysis. We describe here that nanostructured porous Au made via dealloying represents a new class of unsupported catalysts with extraordinary activities in important reactions such as CO oxidation. Although nanoporous Au may contain some oxides on the surface, our results demonstrate that it is metallic Au that plays the main role in this catalytic reaction. Furthermore, this material has good low-temperature catalytic stability and is extremely CO tolerant. Copyright © 2006 American Chemical Society.

引用

页码：42 / 43

页数：2

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