Aggregation of tripodal thallium(I) amides through weak Tl-I center dot center dot center dot Tl-I interactions

被引：24

作者：

Hellmann, KW

Gade, LH

Scowen, IJ

McPartlin, M

机构：

[1] UNIV WURZBURG,INST ANORGAN CHEM,D-97074 WURZBURG,GERMANY

[2] UNIV N LONDON,SCH APPL CHEM,LONDON N7 8DB,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 22期

关键词：

D O I：

10.1039/cc9960002515

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal exchange between the lithium amide MeSi[SiMe(2)N-(Li)Bu(t)](3) and TICl yields the corresponding thallium amide MeSi[SiMe(2)N(Tl)Bu(t)](3) 1 which aggregates in the solid through weak attractive TI TI interactions to form infinite molecular chains; competing redox chemistry leads to the dimetallated species HC[SiMe(2)N(Tl)Bu(t)](2)[SiMe(2)NHBu(t)] 2 in the analogous metal-exchange process involving the trisilylmethane derivative.

引用

收藏

页码：2515 / 2516

页数：2

相关论文

共 18 条

[1] SELF-ASSEMBLING COLUMNAR ORGANIZATION IN THALLIUM(I) BETA-DIKETONATES - FROM CRYSTALLINE PHASES TO LIQUID-CRYSTALS [J].

ATENCIO, R ;

BARBERA, J ;

CATIVIELA, C ;

LAHOZ, FJ ;

SERRANO, JL ;

ZURBANO, MM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (25) :11558-11559

[2] METALATION OF MULTIFUNCTIONAL SECONDARY-AMINES - THE STRUCTURAL CHARACTERIZATION OF THE TRIPODAL LITHIUM AMIDES (H3CC[CH2N(LI)R]3)3 [J].

GADE, LH ;

MAHR, N .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (04) :489-494

[3] TRISILYLMETHANE AS A STRUCTURAL BACKBONE IN MULTIFUNCTIONAL LITHIUM AMIDES - SYNTHESES AND STRUCTURES OF HC((CH3)2SIN(LI)-T-BU)3 AND ITS SOLVATE HC((CH3)2SIN(LI)-T-BU)3.2THF [J].

GADE, LH ;

BECKER, C ;

LAUHER, JW .

INORGANIC CHEMISTRY, 1993, 32 (11) :2308-2314

[4] STRUCTURES AND DYNAMICS OF THE TRIPODAMIDE LIGAND TRANSFER REAGENTS [H3CC(CH2N(LI)SI(CH3)(3))(3)(L)(3)] (L=THF, HMPTA) [J].

HELLMANN, KW ;

GADE, LH ;

LI, WS ;

MCPARTLIN, M .

INORGANIC CHEMISTRY, 1994, 33 (25) :5974-5977

[5] TLI-TLI INTERACTIONS IN THE MOLECULAR-STATE - AN MO ANALYSIS [J].

JANIAK, C ;

HOFFMANN, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (12) :1688-1690

[6] TL(I)-TL(I) AND IN(I)-IN(I) INTERACTIONS - FROM THE MOLECULAR TO THE SOLID-STATE [J].

JANIAK, C ;

HOFFMANN, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (16) :5924-5946

[7]

Janiak C., 1989, Angew. Chem, V101, P1706, DOI 10.1002/ange.19891011216

[8] (1,1',3,3'-TETRA-TERT-BUTYL-5,5'-PENTAFULVALENE)DITHALLIUM - SYNTHESIS AND CRYSTAL-STRUCTURE - A CONTRIBUTION TO THE DISCUSSION OF NONCLASSICAL TL(I)-TL(I) INTERACTIONS [J].

JUTZI, P ;

SCHNITTGER, J ;

HURSTHOUSE, MB .

CHEMISCHE BERICHTE, 1991, 124 (08) :1693-1697

[9] THALLIUM(I)-BIS(TRIMETHYLSILYL)AMIDE [J].

KLINKHAMMER, KW ;

HENKEL, S .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 480 (1-2) :167-171

[10]

KREBS B, 1992, UNKONVENTIONNELLE WE