Rhodium-catalysed substitutive arylation of cis-allylic diols with arylboroxines

被引：58

作者：

Miura, Tomoya ^{[1
]}

Takahashi, Yusuke ^{[1
]}

Murakami, Masahiro ^{[1
]}

机构：

[1] Kyoto Univ, Dept Synth Chem & Biol Chem, Kyoto 6158510, Japan

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 06期

关键词：

D O I：

10.1039/b612710j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Substitutive arylation of cis-allylic diols occurs upon treatment with arylboroxines in the presence of a rhodium(I) catalyst; the reaction proceeds through the addition of an intermediate arylrhodium(I) species across the carbon-carbon double bond and subsequent beta-oxygen elimination.

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页码：595 / 597

页数：3

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