First open-framework zinc germanates by a molecular templating route

被引:43
作者
Bu, XH [1 ]
Feng, PY [1 ]
Stucky, GD [1 ]
机构
[1] Univ Calif Santa Barbara, Dept Chem, Santa Barbara, CA 93106 USA
关键词
D O I
10.1021/cm001006q
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Despite the recent progress in the synthesis of new germanates, no zinc germanate has been synthesized by using a molecular templating route. A unique type of zincogermanate framework has now been prepared by using ethylenediamine as the structure-directing agent. The three-dimensional framework can be simply described as the face-centered packing of an elongated neutral cluster unit, Ge9O18.
引用
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页码:1811 / +
页数:4
相关论文
共 22 条
[1]  
BEHRENS P, 1996, COMPREHENSIVE SUPRAM, V7, P721
[2]  
Breck D.W, 1974, ZEOLITE MOL SIEVES
[3]   Large-cage zeolite structures with multidimensional 12-ring channels [J].
Bu, XH ;
Feng, PY ;
Stucky, GD .
SCIENCE, 1997, 278 (5346) :2080-2085
[4]   Hydrothermal synthesis and structural characterization of zeolite-like structures based on gallium and aluminum germanates [J].
Bu, XH ;
Feng, PY ;
Gier, TE ;
Zhao, DY ;
Stucky, GD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (51) :13389-13397
[5]   Novel germanate zeolite structures with 3-rings [J].
Bu, XH ;
Feng, PY ;
Stucky, GD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (43) :11204-11205
[6]   Isolation of germanate sheets with three-membered rings: A possible precursor to three-dimensional zeolite-type germanates [J].
Bu, XH ;
Feng, PY ;
Stucky, GD .
CHEMISTRY OF MATERIALS, 1999, 11 (12) :3423-+
[7]  
Cascales C, 1999, ANGEW CHEM INT EDIT, V38, P2436, DOI 10.1002/(SICI)1521-3773(19990816)38:16<2436::AID-ANIE2436>3.0.CO
[8]  
2-W
[9]   Ordered mesoporous materials [J].
Ciesla, U ;
Schüth, F .
MICROPOROUS AND MESOPOROUS MATERIALS, 1999, 27 (2-3) :131-149
[10]   Crystal structures of the α and β forms of K2ZnGeO4 [J].
Colbeau-Justin, C ;
Wallez, G ;
Elfakir, A ;
Quarton, M .
JOURNAL OF SOLID STATE CHEMISTRY, 1997, 134 (01) :59-66