First open-framework zinc germanates by a molecular templating route

被引:43
作者
Bu, XH [1 ]
Feng, PY [1 ]
Stucky, GD [1 ]
机构
[1] Univ Calif Santa Barbara, Dept Chem, Santa Barbara, CA 93106 USA
关键词
D O I
10.1021/cm001006q
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Despite the recent progress in the synthesis of new germanates, no zinc germanate has been synthesized by using a molecular templating route. A unique type of zincogermanate framework has now been prepared by using ethylenediamine as the structure-directing agent. The three-dimensional framework can be simply described as the face-centered packing of an elongated neutral cluster unit, Ge9O18.
引用
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页码:1811 / +
页数:4
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