Structure-directing role of organoamine ligands in the self-assembly of novel bimetallic oxides

被引：89

作者：

Hagrman, D

Warren, CJ

Haushalter, RC

Seip, C

O'Connor, CJ

Rarig, RS

Johnson, KM

LaDuca, RL

Zubieta, J

机构：

[1] Syracuse Univ, Dept Chem, Syracuse, NY 13244 USA

[2] Symyx Technol, Santa Clara, CA 95051 USA

[3] Univ London Kings Coll, Briarcliff Manor, NY USA

[4] Univ New Orleans, New Orleans, LA 70148 USA

来源：

CHEMISTRY OF MATERIALS | 1998年 / 10卷 / 11期

关键词：

D O I：

10.1021/cm980439e

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The introduction of dipodal nitrogen-donor ligands of varying extensions and the relative orientations of these donor groups have a profound influence on the microstructures of bimetallic copper molybdenum oxide phases. Tethered pyridyl donors yield Cu-Mo-O networks while pyrazine and pyrimidine are associated with three-dimensional Cu-Mo-O substructure frameworks with the organic components occupying well-defined channels, as illustrated alongside for [Cu-2(pyrimidine)(Mo3O10)] (CUMO-6).

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页码：3294 / +

页数：5

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