Functionalization of [60]fullerene by photoinduced electron transfer (PET): Syntheses of 1-substituted 1,2-dihydro [60]fullerenes

被引：45

作者：

Siedschlag, C

Luftmann, H

Wolff, C

Mattay, J

机构：

[1] CHRISTIAN ALBRECHTS UNIV KIEL, INST ORGAN CHEM, D-24098 KIEL, GERMANY

[2] UNIV MUNSTER, INST ORGAN CHEM, D-48149 MUNSTER, GERMANY

来源：

TETRAHEDRON | 1997年 / 53卷 / 10期

关键词：

D O I：

10.1016/S0040-4020(97)00078-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[60]Fullerene is irradiated in the presence of the electron transfer sensitizer 9,10-dicyanoanthracene (DCA) under cosensitization with biphenyl. The generated radical cation C-60(.+) reacts with H-donors such as tert-butylmethyl ether, propionaldehyde and alcohols to give 1:1-adducts, the 1-substituted 1,2-dihydro[60]fullerenes. (C) 1997 Elsevier Science Ltd.

引用

页码：3587 / 3592

页数：6

共 20 条

[1] THE EFFECT OF META-CYANO OR PARA-CYANO SUBSTITUTION ON THE REACTIVITY OF THE RADICAL CATIONS OF ARYLALKENES AND ALKANES - RADICAL IONS IN PHOTOCHEMISTRY .34. [J].