Phosphonate derivatives of pyridine grafted onto oxide nanoparticles

被引:19
作者
Frantz, R [1 ]
Granier, M [1 ]
Durand, JO [1 ]
Lanneau, GF [1 ]
机构
[1] Univ Montpellier 2, UMR 5637, F-34095 Montpellier 05, France
关键词
D O I
10.1016/S0040-4039(02)02240-2
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The synthesis of phosphonate derived stilbazole 1 by using a Heck reaction is described. The reactivity of the pyridine moiety is studied. After hydrolysis of the ethyl phosphonate groups, the grafting of phosphonic acid derived stilbazole 5 on metal oxides TiO2 or SnO2 is reported. The accessibility and reactivity of the pyridine moiety at the surface is demonstrated. (C) 2002 Published by Elsevier Science Ltd.
引用
收藏
页码:9115 / 9117
页数:3
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