Amidinato- and Guanidinato-Cobalt(I) Complexes: Characterization of Exceptionally Short Co-Co Interactions

被引：121

作者：

Jones, Cameron ^{[1
]}

Schulten, Christian ^{[1
,2
]}

Rose, Richard P. ^{[1
,2
]}

Stasch, Andreas ^{[1
]}

Aldridge, Simon ^{[3
]}

Woodul, William D. ^{[1
]}

Murray, Keith S. ^{[1
]}

Moubaraki, Boujemaa ^{[1
]}

Brynda, Marcin ^{[4
]}

La Macchia, Giovanni ^{[4
]}

Gagliardi, Laura ^{[4
,5
,6
]}

机构：

[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

[2] Cardiff Univ UK, Sch Chem, Cardiff, S Glam, Wales

[3] Univ Oxford, Oxford OX1 2JD, England

[4] Univ Geneva, Dept Chim Phys, CH-1211 Geneva 4, Switzerland

[5] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

[6] Univ Minnesota, Inst Supercomp, Minneapolis, MN 55455 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 40期

基金：

瑞士国家科学基金会; 英国工程与自然科学研究理事会; 澳大利亚研究理事会;

关键词：

cobalt; magnetic properties; metal-metal interactions; N ligands; METAL BOND LENGTHS; CHEMISTRY; COORDINATION; IRON; CR;

D O I：

10.1002/anie.200900780

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

CoCo loco! Ligand-bridged dimers (see picture) with the shortest known Co-Co interactions are the first amidinato and guanidinato cobalt(I) complexes. The nature of the interactions has been probed by magnetic and theoretical investigations, and has been shown to be multiconfigurational. Preliminary reactivity studies of the complexes have also been carried out. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7406 / 7410

页数：5

共 35 条

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Aullón G, 2001, EUR J INORG CHEM, P3031

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