Reactivity of a Co(I) [N2P2] complex with azides:: evidence for a transient Co(III) imido species

被引：29

作者：

Chomitz, Wayne A. ^{[1
]}

Arnold, John ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 31期

关键词：

D O I：

10.1039/b804754e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of a monomeric Co(I) complex supported by a multidentate monoanionic [N(2)P(2)] ligand is described; interaction with aryl azides at low temperature generates a species whose reactivity is consistent with imido (''Co=NR'') character.

引用

页码：3648 / 3650

页数：3

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