A facile synthesis of (+/-)-mintlactone

被引：11

作者：

Tanyeli, C

Caliskan, Z

Demir, AS

机构：

[1] Department of Chemistry, Middle East Technical University

来源：

SYNTHETIC COMMUNICATIONS | 1997年 / 27卷 / 19期

关键词：

D O I：

10.1080/00397919708005649

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(+/-)-Mintlactone has been synthesized by applying a novel effective synthetic sequence. 4-Methylcyclohexanone was subjected to acetoxylation with Pb(OAc)(4). Hydrolysis followed by reaction with 2-chloroprogionyl chloride,then treatment with triethyl phosphite and, finally, Horner-Emmons-type intramolecular cyclization afforded (+/-)-Mintlactone.

引用

页码：3471 / 3476

页数：6

共 11 条

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[9] CHEMICAL-COMPOSITION OF FRAGRANT MATERIALS .4. A NEW KETO-ALCOHOL, (-)-MINTLACTONE, (+)-ISOMINTLACTONE AND MINOR COMPONENTS IN PEPPERMINT OIL
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