Unprecedented solvent-induced acceleration of free-radical propagation of methyl methacrylate in ionic liquids

被引：145

作者：

Harrisson, S ^{[1
]}

Mackenzie, SR ^{[1
]}

Haddleton, DM ^{[1
]}

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 23期

关键词：

D O I：

10.1039/b209479g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The rate of propagation in the free-radical polymerization of methyl methacrylate in an ionic liquid has been determined and shows unprecedented solvent-induced acceleration, partially explaining the surprising increase in overall rates of polymerization and molecular weights in these solvents.

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收藏

页码：2850 / 2851

页数：2

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