Effects of size, shape and floatage of Cu particles on the low infrared emissivity coatings

被引:93
作者
Yu, Huijuan [1 ]
Xu, Guoyue [1 ]
Shen, Xingmei [1 ]
Yan, Xiaoxing [1 ]
Shao, Chunming [1 ]
Hu, Chen [1 ]
机构
[1] Nanjing Univ Aeronaut & Astronaut, Coll Mat Sci & Technol, Nanjing 210016, Peoples R China
基金
中国国家自然科学基金;
关键词
Infrared emissivity; Coating; Pigment particles; EPDM; Leafing;
D O I
10.1016/j.porgcoat.2009.07.002
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Low infrared emissivity coating was prepared by the copper (Cu) particles and ethylene-propylene-diene monomer (EPDM) binder. The effect of size, shape and floatage of Cu particles on infrared emissivity of the coatings was systematically investigated. The results indicated that the optimized Cu particles with the minimum coating emissivity are several micron-sized, flaky and high-leafing, exhibiting 0.78, 0.72 and 0.10 emissivity value, respectively. The formation of low infrared emissivity coatings depends strongly on the floatage of Cu particles, not the size or shape, and the results obtained by leafing aluminum (Al) and bismuth oxide (Bi2O3) pigment are in good agreement with this standpoint. A theoretical model was proposed to account for the mechanism. which indicated that the low porosity of the coatings with leafing pigments plays an important role in the formation of low emissivity coatings. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:161 / 166
页数:6
相关论文
共 10 条
[1]  
*ASTM, D48088 ASTM
[2]   Effects of tin on IR reflectivity, thermal emissivity, Hall mobility and plasma wavelength of sol-gel indium tin oxide films on glass [J].
Biswas, PK ;
De, A ;
Pramanik, NC ;
Chakraborty, PK ;
Ortner, K ;
Hock, V ;
Korder, S .
MATERIALS LETTERS, 2003, 57 (15) :2326-2332
[3]   Synthesis, characterization and infrared emissivity study of polyurethane/TiO2 nanocomposites [J].
Chen, Jing ;
Zhou, Yuming ;
Nan, Qiuli ;
Sun, Yanqing ;
Ye, Xiaoyun ;
Wang, Zhiqiang .
APPLIED SURFACE SCIENCE, 2007, 253 (23) :9154-9158
[4]   The application of nanosized silver colloids in far infrared low-emissive coating [J].
Chou, Kan-Sen ;
Lu, Yu-Chieh .
THIN SOLID FILMS, 2007, 515 (18) :7217-7221
[5]   Cl- induced synthesis of submicron cubic copper particles in solution [J].
Hu, Minyi ;
Zhou, Kanggen ;
Wang, Chongguo ;
Xu, Rui .
JOURNAL OF UNIVERSITY OF SCIENCE AND TECHNOLOGY BEIJING, 2008, 15 (05) :659-664
[6]  
KONDIS, 1986, Patent No. 4629512
[7]   Characterisation and stability of low-emittance multiple coatings for glazing applications [J].
Leftheriotis, G ;
Yianoulis, P .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1999, 58 (02) :185-197
[8]   Structure and infrared emissivity of silicon-containing polyimide/BaTiO3 nanocomposite films [J].
Lin, BP ;
Liu, HJ ;
Zhang, SX ;
Yuan, CW .
JOURNAL OF SOLID STATE CHEMISTRY, 2004, 177 (10) :3849-3852
[9]   Long-distance oxygen plasma sterilization: Effects and mechanisms [J].
Liu, Hongxia ;
Chen, Jierong ;
Yang, Liqing ;
Zhou, Yuan .
APPLIED SURFACE SCIENCE, 2008, 254 (06) :1815-1821
[10]   Synthesis and infrared emissivity study of collagen-g-PMMA/Ag@TiO2 composite [J].
Ye, Xiaoyun ;
Zhou, Yuming ;
Chen, Jing ;
Sun, Yanqing .
MATERIALS CHEMISTRY AND PHYSICS, 2007, 106 (2-3) :447-451