Highly selective synthesis of biphenyl by the Pd(OAc)2/HPA/O2/AcOH catalyst system

被引：16

作者：

Okamoto, M ^{[1
]}

Watanabe, M ^{[1
]}

Yamaji, T ^{[1
]}

机构：

[1] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Higashi Ku, Fukuoka 8128581, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 664卷 / 1-2期

关键词：

biphenyl; oxidative dimerization; benzene; Pd(OAc)(2); H3PMo12O40;

D O I：

10.1016/S0022-328X(02)01901-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new catalytic system, Pd(OAc)(2)/H3PMo12O40/O-2/AcOH-H2O (2:1), has been found to give biphenyl by the oxidative dimerization of benzene with 100% selectivity and 19% yield under the conditions of 130 degreesC, 10 atm and 4 h. PdHPMo12O40 itself was also found to act as a catalyst to give 95% of selectivity of biphenyl with a lower yield. A plausible mechanism of this system is also discussed. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：59 / 65

页数：7