Compatibilization of PP/Vectra B "in situ" composites by means of an ionomer

被引:29
作者
Vallejo, FJ
Eguiazábal, JI
Nazábal, J
机构
[1] Univ Basque Country, EHU, Fac Quim, Dept Ciencia & Tecnol Polimeros, E-20080 San Sebastian, Spain
[2] Univ Basque Country, EHU, Fac Quim, Inst Mat Polimericos, E-20080 San Sebastian, Spain
关键词
polypropylene; Vectra B; ionomer;
D O I
10.1016/S0032-3861(99)00864-2
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Ionomer addition has been investigated as a compatibilizer for the immiscible polypropylene (PP)/Vectra B 950 (VB). Both modified and unmodified blends as a reference, with VB contents up to 30% were obtained by direct injection moulding. The crystallinity of PP/VB was barely influenced by the presence of the ionomer. The compatibilization leads to the presence of thinner fibres that broke during testing. Compatibilization reduced toughness, but at VB contents of 15 wt% or more, both the modulus of elasticity and the tensile strength significantly increased with respect to the uncompatibilized blends. The properties of both compatibilized and uncompatibilized blends, as a whole, were similar in the case of PP modified by either maleic anhydride or ionomer addition. However, favourable experimental conditions such as thinner specimens or higher compatibilizer content were used in the case of maleic anhydride modified PP. This indicates a more important positive effect: on compatibilization by means of ionomer addition. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:6311 / 6321
页数:11
相关论文
共 65 条
[1]  
ACIERNO D, 1993, PROCESSING PROPERTIE
[2]  
BAIRD DG, 1997, Patent No. 5621041
[3]   REPROCESSING OF LIQUID-CRYSTAL POLYMERS - EFFECTS ON STRUCTURE AND MECHANICAL-PROPERTIES [J].
BASTIDA, S ;
EGUIAZABAL, JI ;
NAZABAL, J .
JOURNAL OF APPLIED POLYMER SCIENCE, 1995, 56 (11) :1487-1494
[4]   THE MECHANISM OF SKIN-CORE MORPHOLOGY FORMATION IN EXTRUDATES OF POLYCARBONATE LIQUID-CRYSTALLINE POLYMER BLENDS [J].
BEERY, D ;
KENIG, S ;
SIEGMANN, A ;
NARKIS, M .
POLYMER ENGINEERING AND SCIENCE, 1993, 33 (23) :1548-1558
[5]  
BEERY D, 1991, POLYM ENG SCI, V31, P451, DOI 10.1002/pen.760310612
[6]   THE MORPHOLOGY OF EXTRUDED BLENDS CONTAINING A THERMOTROPIC LIQUID-CRYSTALLINE POLYMER [J].
BLIZARD, KG ;
FEDERICI, C ;
FEDERICO, O ;
CHAPOY, LL .
POLYMER ENGINEERING AND SCIENCE, 1990, 30 (22) :1442-1453
[7]   DYNAMIC RHEOLOGICAL PROPERTIES OF POLYETHERIMIDE/POLYETHERETHERKETONE/LIQUID CRYSTALLINE POLYMER TERNARY BLENDS [J].
BRETAS, RES ;
COLLIAS, D ;
BAIRD, DG .
POLYMER ENGINEERING AND SCIENCE, 1994, 34 (19) :1492-1496
[8]   Effect of compatibilizers on mechanical properties and morphology of in-situ composite film of thermotropic liquid crystalline polymer/polypropylene [J].
Bualek-Limcharoen, S ;
Samran, J ;
Amornsakchai, T ;
Meesiri, W .
POLYMER ENGINEERING AND SCIENCE, 1999, 39 (02) :312-320
[9]   In situ compatibilized polypropylene/liquid crystalline polymer blends [J].
Chiou, YP ;
Chiou, KC ;
Chang, FC .
POLYMER, 1996, 37 (18) :4099-4106
[10]   Separation of a thermotropic liquid crystalline polymer from polypropylene composites [J].
Collier, MC ;
Baird, DG .
POLYMER COMPOSITES, 1999, 20 (03) :423-435