Anomalous reactions of the diamine Me2NCH2NMe2 with nickel(II) and cobalt(II)

被引：11

作者：

Hitchcock, PB ^{[1
]}

Handley, DA ^{[1
]}

Lee, TH ^{[1
]}

Leigh, GJ ^{[1
]}

机构：

[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 24期

关键词：

D O I：

10.1039/b207818j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The diamine Me2NCH2NMe2 (tmmn) is capable of forming simple adducts with most metal(II) ions of the first transition series, but with nickel and cobalt a variety of additional products can be obtained from its reaction with the dihalides. The diamine may be monodentate or bidentate, it may (formally) lose a hydride to generate a cation, and each N-C bond may break, generating new products containing additional methyl groups or the ions (Me2NH2)(+) or (Me2N=CH2)(+).

引用

页码：4720 / 4725

页数：6

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