A route to functionalized (η3-allyl)dicarbonylnitrosyliron complexes:: Regio- and stereoselective acylmetallation of allenes

被引：7

作者：

Itoh, K

Nakanishi, S

Takata, T

机构：

[1] Osaka Prefectural Coll Technol, Dept Ind Chem, Osaka 5728572, Japan

[2] Univ Osaka Prefecture, Grad Sch Engn, Dept Appl Chem, Osaka 5998531, Japan

来源：

CHEMISTRY LETTERS | 2000年 / 06期

关键词：

D O I：

10.1246/cl.2000.672

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Allenes regio- and stereoselectively react with alkyl halides in the presence of tetrabutylammonium tricarbonylnitrosyl ferrate to give anti-(eta(3)-2-acylallyl)dicarbonylnitrosyliron complexes in good yields. The reaction provides a convenient method for preparation of di- and trisubstituted eta(3)-allyl iron complexes with acyl groups at the central carbon of the allylic ligands.

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页码：672 / 673

页数：2

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