Twelve-connected porous metal-organic frameworks with high H2 adsorption

被引:217
作者
Jia, Junhua
Lin, Xiang
Wilson, Claire
Blake, Alexander J.
Champness, Neil R.
Hubberstey, Peter
Walker, Gavin
Cussen, Edmund J.
Schroder, Martin [1 ]
机构
[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
[2] Univ Nottingham, Sch Mech Mat & Mfg Engn, Nottingham NG7 2RD, England
关键词
D O I
10.1039/b614254k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The twelve-connected metal-organic frameworks {[Ni-3(OH)(L)(3)].n(solv)}(infinity) 1 and {[Fe-3(O)(L)(3)].n(solv)}(infinity) 2 [LH2=pyridine-3,5-bis(phenyl-4-carboxylic acid)] have been prepared and characterised: these materials can be desolvated to form porous materials that show adsorption of H-2 up to 4.15 wt% at 77 K.
引用
收藏
页码:840 / 842
页数:3
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